Material Data Sheet

• Proprietary SM2050 series. TGP-0801 (latest revision)
• API 5CT / ISO11960
• NACE MR0175 / ISO 15156
• API RP 5C1 / ISO 10405
• API 5CRA  / ISO 13680
• VAM Book
• Nippon Steel Storage and handling procedure for CRA materials

Corrosive environments featuring the combined presence of CO₂ + H₂S + S⁰ (elemental sulfur) + Chloride, in temperatures up to 204 °C (400 °F).

Its primary function is Tubing and Liner, sections permanently exposed to production fluids

Final material application will depend upon CO₂, H₂S, S⁰, Temperature, pH and expected Chlorides content. For a more detailed assessment please contact Nippon Steel engineers.

(mass %)

UNS Number: N06250

In wet combined CO₂ & H₂S environments, for temperatures exceeding 177°C (350°F) or in wet combined CO₂ & H₂S environments containing elemental sulphur, usage of SM2050 is recommendable from H₂S partial pressures exceeding 0.1 bar:

• for lower H₂S partial pressure ranging between 0.1 to 1.0 bar, these  materials should be considered depending upon the combination of critical variables such as pH, Chloride content, S⁰ and temperature
• for H₂S partial pressures exceeding 1.0 bar the only metallurgical solution to counter corrosion is to consider Austenitic Fe base or Nickel base materials.

Since H₂S and specifically elemental sulphur are potent pitting agents, a superior passivation film composed of Ni-S, Cr-O & Mo-S is required to maintain stability and protect the bulk material from corrosion attack up to a defined temperature threshold in wet combined CO2 & H2S environment. This is achieved through alloying of Cr-Ni & Mo.

SM2050 is a nominal 11% Molybdenum material recognized by ISO-13680 as Group 4 Category 22-52-11.

This material does not have a specific equivalence in NACE MR0175 /ISO 15156-3 and is located in between material type 4d and 4e (please refer to Fig. 1).

Fig 1: NACE MR0175 / ISO 15156-3 2003 Table A12

For Type 4e material (close to SM2050 material), NACE MR0175 /ISO 15156-3 indicates the following application limits as a general guideline:

Fig 2: Material 4e application boundaries per NACE MR0175 / ISO 15156-3 2003 (Ref. Table A-14)

According to NACE MR0175 / ISO 15156-3 2003, final material selection for the intended service will be equipment user’s responsibility and detailed information exchange with manufacturer is highly recommendable.

Fig 3 below represents Nippon Steel SCC limits on various Austenitic materials.

Fig. 3: Relation between testing temperature and Mo content of Nickel Alloy in
H₂S- Cl^- environment in SSRT (25% NaCl+ CH₃COOH, 0.7 MPa (100 psi) H₂S)

Fig 4 below represents material SSC resistance in presence of elemental sulphur, as a function of Molybdenum content (Mo),

Fig. 4: Relationship between testing temperature and Mo content
of Nickel Alloy in an elemental S-containing sour environment
(25% NaCl+ 1 g/l S, 1.0 MPa (145 psi) H₂S, 1.0 MPa (145 psi) CO₂),
4 point bent beam with notch - 100% SMYS (110 ksi) – 336 h

Nippon Steel’s position concerning SM2050 application limits is in line with ISO 15156/NACE MR0175 limits highlighted in Fig.2 except for temperatures ranging between 204 and 232°C where Nippon Steel does recommend fit for purpose validation tests.

For additional information about material performances please contact Nippon Steel engineers.

While state-of-the-art HSE rules are applied throughout Nippon Steel manufacturing process, proprietary and specific HSE regulations shall be applied along the life cycle of the pipe until it reaches its final position in the well, according to each operator’s rules. This particularly applies to all phases of handling and transportation, assembly on the rig floor, and rig return if applicable. OCTG are heavy and by nature unstable. Special care shall be paid to potential risks of injury whenever handling OCTGs. Walking on pipes shall be avoided at all times. Usage of Personal Protection Equipments (PPE) is mandatory. Equipment and procedures will be established to capture the possible wastes generated during maintenance (cleaning, coating, doping) and disposed according to local regulations. This applies in particular to storage dope, running dope, or cleaning water wastes.

Best practices for transportation, handling and storage of OCTG in general are covered by ISO 10405 / API RP5C1. VAM Book is also a good source of handling practices for VAM connections. In addition to these general rules, specific care is recommended pertaining to SM2050, because improper handling could affect the material performances and by extension the corrosion resistance :

• Prevention of Spot Hardening
• Prevention of Iron contamination
• Adapted running equipments and practices
• Prevention of corrosion on rig returns, particularly in presence of completion fluids

For more specific information please refer to Nippon Steel Storage and handling procedure for CRA materials or contact Nippon Steel engineers.